6. Agent 99 in "Get Smart" Eminently capable and devastatingly gorgeous, Anne Hathaway's Agent 99 was the only CONTROL agent, aside from Maxwell Smart, whose identity hadn't been compromised at the start of the 2008 film. (The character was updated from the version Barbara Feldon played in the original 1960s show.) The series of ever-more-fabulous couture getups she donned over the course of her and Maxwell's mission wasn't exactly believable, but it sure was impressive.